Tetraaquabis[2-(thiosemicarbazonomethyl)benzenesulfonato]manganese(II)
نویسندگان
چکیده
In the title compound, [Mn(C(8)H(8)N(3)O(3)S(2))(2)(H(2)O)(4)], the Mn(II) atom (site symmetry ) adopts a slightly distorted octa-hedral MnO(6) geometry. The mol-ecular conformation is supported by N-H⋯N and O-H⋯O hydrogen bonds. In the crystal, mol-ecules inter-act by O-H⋯O, O-H⋯S, N-H⋯O and N-H⋯S hydrogen bonds, thereby forming (011) sheets.
منابع مشابه
Tetraaquabis[2-(thiosemicarbazonomethyl)benzenesulfonato]calcium(II)
In the title compound, [Ca(C(8)H(8)N(3)O(3)S(2))(2)(H(2)O)(4)], the Ca atom (site symmetry ) adopts a slightly distorted octa-hedral CaO(6) geometry and the mol-ecular conformation is stabilized by intra-molecular N-H⋯N inter-actions. In the crystal, the mol-ecules are linked by O-H⋯O, O-H⋯S, N-H⋯O and N-H⋯S hydrogen bonds.
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The chemical name in the title of the paper by Hu [Acta Cryst. (2008), E64, m772] is corrected.[This corrects the article DOI: 10.1107/S1600536808012464.].
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